Helium balloons work by the same law of buoyancy. In this case, the helium balloon that you hold by a string is floating in a “pool” of air (when you stand underwater at the bottom of a swimming pool, you are standing in a “pool of water” maybe 10 feet deep — when you stand in an open field you are standing at the bottom of a “pool of air” that is many miles deep). The helium balloon displaces an amount of air (just like the empty bottle displaces an amount of water). As long as the helium plus the balloon is lighter than the air it displaces, the balloon will float in the air.
Why are helium and hydrogen so much lighter than air? It’s because the hydrogen and helium atoms are lighter than a nitrogen atom. They have fewer electrons, protons and neutrons than nitrogen atoms do, and that makes them lighter (the approximate atomic weight of hydrogen is 1, helium is 4 and nitrogen is 14). Approximately the same number of atoms of each of these elements fills approximately the same amount of space. Therefore, the gases made of lighter atoms are lighter.
Picture Credit : Google