Armalcolite is a titanium-rich mineral with the chemical formula (Mg,Fe2+)Ti2O5. It was first found at Tranquility Base on the Moon in 1969 during the Apollo 11 mission, and is named for Armstrong, Aldrin and Collins, the three Apollo 11 astronauts. Together with tranquillityite and pyroxferroite, it is one of three new minerals that were discovered on the Moon. Armalcolite was later identified at various locations on Earth and has been synthesized in the laboratory
Armalcolite was originally found on the Moon, in the Sea of Tranquility at Tranquility Base, and also in the Taurus–Littrow valley and the Descartes Highlands. The largest amounts were provided by the Apollo 11 and 17 missions. It was later identified on Earth from samples of lamproite dikes and plugs taken in Smoky Butte, Garfield County, Montana, US. On the Earth, it also occurs in Germany (Nördlinger Ries impact crater in Bavaria), Greenland (Disko Island), Mexico (El Toro cinder cone, San Luis Potosí), South Africa (Jagersfontein, Bultfontein and Dutoitspan kimberlite mines), Spain (Albacete Province and Jumilla, Murcia), Ukraine (Pripyat Swell), United States (Knippa quarry, Uvalde County, Texas and Smoky Butte, Jordan, Montana) and Zimbabwe (Mwenezi District). Armalcolite was also detected in lunar meteorites, such as Dhofar 925 and 960 found in Oman.
Armalcolite is a minor mineral found in titanium-rich basalt rocks, volcanic lava and sometimes granite pegmatite, ultramafic rocks, lamproites and kimberlites. It is associated with various mixed iron-titanium oxides, graphite, analcime, diopside, ilmenite, phlogopite and rutile. It forms elongated crystals up to about 0.1–0.3 mm in length embedded in a basalt matrix. Petrographic analysis suggests that armalcolite is typically formed at low pressures and high temperatures.
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