Plants can prevent pollution of environment in many ways. However, the answer is restricted to prevention of air pollution by trees.
The major components of atmosphere are nitrogen (78.08 per cent) and oxygen (20.95 per cent) (major) with minor components are argon and carbon dioxide (0.0314 per cent) and many trace elements such as neon, helium, nitrous oxide, methane, carbon monoxide, sulphur dioxide, ozone, ammonia and aerosols (colloidal sized particles) are also present.
The ratio of these components is changing very fast due to increased human activities like fossil fuel burning, afforestation and changes in land use. They result in the liberation of tones of carbon dioxide, carbon monoxide, methane and aerosols into the atmosphere. The server human interference over the last century is said to have strained the buffering capability of nature.
Trees help reduce the pollution in more than one way. First, they act as sink for carbon dioxide. Through photosynthesis they synthesize carbohydrates using carbon dioxide, water and sunlight. This way thousands of tonnes of carbon dioxide are trapped by the trees. By the same process, trees release oxygen, which is needed by other living organisms. They also help in cooling of the atmosphere by transpiration, a process in which water is given up by plants as vapour. I addition, aerosols and dust particles (components of atmosphere pollution) settle on the dense foliage of trees. Thus trees, especially the tall ones with dense foliage around houses and industrial establishments, reduce aerosol and dust pollution by acting as barriers or curtains.