Which is Europe's largest nuclear plant?

The Zaporizhzhia plant in southern Ukraine is Europe's largest nuclear plant. It was captured by Russia in March, following its invasion of Ukraine in February 2022, raising global fears of a nuclear disaster. Bouts of shelling in the region followed, prompting calls for an urgent inspection of the facility by experts of the International Atomic Energy Agency (IAEA). But what is IAEA and what are its functions? Let's find out.

The International Atomic Energy Agency, abbreviated as IAEA, is the United Nations' nuclear watchdog. The centre for nuclear cooperation and safeguards, the IAEA seeks to promote safe, secure, and peaceful use of nuclear technologies contributing to international security.

It was U.S. President Eisenhower's "Atoms for Peace" address to the U.N. General Assembly (UNGA) in December 1953 that sowed the seeds for the creation of the agency. The IAEA was established in 1957 as an autonomous agency within the U.N family in response to fears arising from the varied uses of nuclear technology.

The IAEA is an autonomous agency with its headquarters in Vienna, Austria. It works with its over 170 member states worldwide to "promote and control the Atom" for peaceful purposes and enable exchange of scientific and technical information between them. Being the international safeguards inspectorate, its mandate includes setting the framework for cooperative efforts to strengthen an international nuclear safety and security regime and verifying whether the member states fulfil their non-proliferation undertakings under the Treaty on the Non-Proliferation of Nuclear Weapons (NPT).

Funded by its member states and other donors, the IAEA runs scientific research labs in Austria, Monaco, and Italy. It reports to the UN General Assembly every year, and to the UN Security Council if need be when there are instances of non-compliance with regard to safeguards and security obligations by member states.

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WHAT IS CARBONATION?

Decaying leaves and plant matter give out carbon dioxide, which is also present in the air around us. Carbon dioxide dissolves in water to create carbonic acid through a process called carbonation. This acid can, over time, dissolve rocks, especially limestone. Limestone is a soft rock that consists mainly of calcium carbonate, which reacts with rainwater, dissolving away to create huge caves and cave complexes.

Carbonation is the chemical reaction between carbon dioxide present in the air, and the hydration compounds of the cement in concrete structures. The rate of carbonation depends on the physical characteristics such as the design, on-site preparation, production and protection, as well as external factors, such as the location and degree of exposure to contaminants and other environmental factors. Carbonation may lead to the corrosion of the reinforcement steel and deterioration of concrete structures.

The carbonation process starts immediately when concrete is exposed to air. Carbon dioxide (CO2) penetrates the concrete through the pores where it reacts with the calcium hydroxide and the moisture in the pores to form calcium carbonate. The carbon dioxide combines with the pore water to form a dilute carbolic acid which acts to reduce the concrete’s alkalinity.

Carbonation reduces the concrete’s natural alkalinity from pH13 to about pH8. Whereas a high pH provides a passivation layer around the steel, at pH below 9.5, the passivation layer breaks down and exposes the reinforcement steel to the corrosive effects of water and air.

When steel rusts, it expands in volume and exerts force on the surrounding concrete, causing the concrete to crack and spall at a rate that increases exponentially if the corrosion is not prevented.

Credit: Corrosionpedia

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WHAT IS HONEYCOMB WEATHERING?

When salt water that collects on the rough surface of rocks, or seeps into cracks, evaporates, it leaves behind salt crystals. Over time, these crystals alter the rock, forming hundreds and thousands of tightly joined pits called honeycombs that are a classic example of both physical and chemical weathering.

Honeycomb weathering occurs throughout the world, but the origin remains a matter of controversy. Wind erosion, exfoliation, frost shattering, and salt weathering have been proposed as explanations, although few attempts have been made to substantiate these hypotheses with chemical or mineralogical studies.

Chemical analyses and field observations indicate that honeycomb weathering in coastal exposures of arkosic sandstone near Bellingham, Washington, results from evaporation of salt water deposited by wave splash. Microscopic examination of weathered surfaces show that erosion results from disaggregation of mineral grains rather than from chemical decomposition. Thin walls separating adjacent cavities seem to be due to protective effects of organic coatings produced by microscopic algae inhabiting the rock surface. Cavity walls are not reinforced by precipitation of elements released by weathering, as has often been suggested at other locations. Honeycomb weathering develops rapidly and can be observed on surfaces that were planar less than a century ago.

Credit: Geo Science World

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Some activities based upon Chemicals.


Chemicals surround us all the time and influence our lives without us even noticing. Here you can see a few more examples of some chemical and physical reactions with everyday chemicals.



Producing gas



Many different chemical reactions produce gas. At home, why not try producing carbon dioxide gas. To do this, mix together vinegar, which is acidic, and baking powder, which is alkaline, in a jar. Make sure the jar is in a sink — watch the bubbles of carbon dioxide erupt over the edge of the jar!



Physical change



Iron filings and sulphur can be mixed together. The iron filings can be easily separated from the mixture as they are attracted by a magnet. This is an example of a physical change. In a physical change, the material changes only its appearance. It is easy to reverse the change because no new substances are formed.



Chemical change



Eggs and bread are mixtures of compounds. When they are heated, new compounds are formed and a chemical reaction has taken place. We cannot undo this change in a simple way. Only complex chemical processes can reverse a chemical change.



How does evaporation work?



Ask an adult to help you boil a solution of salt and water. As the solution is heated, the tiny molecules move more rapidly. The water molecules eventually gain enough energy to fly off as gas. However, there’s not enough energy for the salt to boil, and it is left behind.





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What are various uses of chemicals?


People have always used natural chemicals in their daily lives. Vegetable dyes are used to colour wool and cloth or to make paint. Other chemicals from plants have been used as medicines. Originally, drugs such as penicillin were made from moulds grown naturally. Today, most of our medicines are artificially produced.



Scientists have produced chemicals to help farmers. Fertilizers, spread on the fields, make crops plentiful and strong. Pesticides can be used to kill insects that damage crops. Although chemicals are used to improve our lives, many may be harmful too. For this reason, chemicals are developed and tested in laboratories before they are used.



            Pesticides are sprayed on crops to protect them from being eaten by insects.



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How can we check the nature of chemical without going to Lab?


Red cabbage contains a coloured chemical which acts as an indicator. The blue dye from the cabbage turns pink in acids and green in alkalis. Neutral substances do not make the indicator change colour. Make your own indicator and find out which of the everyday chemicals you have at home are acids or alkalis.



What you need



Red cabbage, a knife, a chopping board, boiling water, 2 bowls, blotting paper, a wooden spoon, clothes pegs, string, milk, soap, lemon juice, bicarbonate of soda and water.



Ask a grown-up to boil some water and chop the cabbage leaves. Put the cabbage leaves in a bowl.



Carefully add the water to the cabbage leaves. Stir the mixture using a wooden spoon. The dye from the cabbage will turn the water blue.



When the solution has cooled, pour the water into another bowl. You don’t need the cabbage leaves anymore.



Dip strips of white blotting paper into the indicator solution. When they are soaked in dye hang them up to dry using string, tied between two points, and some clothes pegs.



Use your indicator paper to test any liquids you may have. (You can also test solids dissolved in water). Just place a few drops of each chemical onto a fresh piece of indicator paper. Try testing chemicals such as soap, milk, lemon juice, and bicarbonate of soda mixed with water. Different substances turn the paper different colours.




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Does Air contain chemical?


Air is a mixture. It contains many gases including nitrogen, oxygen and carbon dioxide. Nitrogen combines with other elements to make compounds called ‘proteins’. Proteins help plants and animals grow, and animals need oxygen to breathe. At the top of a mountain, there is less air than at the bottom. For this reason, mountain climbers sometimes need to take extra oxygen with them.



In sunlight, plants grow by combining carbon dioxide and water to produce more of the chemicals of which they are made. Gases in the air are being used all the time, but they never run out!



The Gas Cycle



We take oxygen from the air, but put back carbon dioxide. Plants take carbon dioxide from the air and, during the day, put back oxygen. Plant and animal bodies contain nitrogen. When they die, this nitrogen returns to the air or soil. Oxygen, carbon dioxide and nitrogen are constantly recycled so we never run out!



            Fighter pilots take their own oxygen supply with them as there is very little air at high altitudes.



            Plants and animals depend on each other to produce the chemicals needed for survival.


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How do chemicals and oils are inter-related?


Crude oil is a thick, black liquid found deep under the Earth’s surface. It was formed millions of years ago from the bodies of tiny animals and plants which lived in the sea. Crude oil is a mixture of many very useful chemicals.



Crude oil is pumped up to the Earth’s surface and is piped to a refinery. Here the different liquids are separated from each other. Some of the liquids, such as petrol and paraffin, can be used as fuels. Others are changed chemically to produce compounds, such as plastics and waxes. Chemicals that come from oil are contained in many of the things we use every day, such as plastic bags and bottles, drain pipes, and some window frames and carpets.



Each liquid chemical boils at a different temperature. The temperature at which it boils is called its ‘boiling point’. When crude oil is heated at the refinery, its temperature slowly rises. The liquid with the lowest boiling point is the first one to boil and form a gas.



This rises upwards, then cools back to a liquid and is collected. As the heating continues, the liquids are separated and collected one by one. The last liquid to be collected is the one with the highest boiling point. This process of separation is called ‘distillation’.



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What are Acids and Alkalis?


Some chemicals are acids or alkalis. Vinegar, lemon juice and sour milk are all weak acids. They all have a similar sharp, sour taste. Oven cleaner, washing soda and toothpaste are all alkalis. Alkalis taste bitter and feel soapy.



Our stomachs contain hydrochloric acid. This acid kills some of the bacteria in our food and helps us to digest our meals. Too much stomach acid causes indigestion. Medicines used to cure stomach pains are often alkalis. When you mix an alkali with an acid, you make a ‘neutral’ solution — neither acidic nor alkaline. Many plants thrive in a soil which is not very acid, so farmers may add lime to the soil. Lime (an alkali) ‘neutralizes’ acidic soil.



Indicators



An ‘indicator’, such as litmus, is a substance that changes colour when it is mixed with an acid or an alkali.



When litmus paper is dipped into lemon juice, it turns red. Alkaline stomach medicine turns it blue. When the acid and the alkali are mixed, a neutral solution is formed which does not colour the litmus.



Car batteries contain a very strong acid solution. Never touch a car battery with bare fingers.



Farmers and gardeners use an alkali – lime – to neutralize acidic soil before planting.





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How do chemicals are separated?


One way of separating chemicals is to use a ‘filter’. A face mask is a type of filter. It is made of material that is full of tiny holes. Air can pass through these holes but particles of dust or paint are too big and get trapped on the outside of the mask.



A filter cannot separate salt from a salt solution. The sodium and chlorine atoms and the water molecules which form a salt solution are small enough to pass through the holes of any filter. If the solution is warmed, the water begins to change into vapour and eventually only salt is left behind. We call this process ‘evaporation’. Stalagmites form by evaporation.



Chromatography



There are three primary colours — red, blue and yellow. Most inks are made by mixing two or more of these colours. To separate ink, a process called chromatography is used. To try this yourself, draw a small circle on blotting paper using a water-based pen. Then put a drop of water on top of the circle. As the water spreads through the blotting paper, it carries the chemicals at different speeds and separates the colours.



Electrolysis



Electrolysis is a process used to separate elements from compounds. An electrical current from a battery is passed through a liquid — called the electrolyte. Some molecules in the electrolyte are positively charged and others are negatively charged. Positively charged particles are attracted to the negative electrode. Negatively charged particles are attracted to the positive electrode. The liquid begins to separate. Electrolysis can be used to purify metals.



A Face mask separates chemicals by preventing large particles from passing through the holes.




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How crystals are formed?


We have seen how to separate salt from a salt solution. If you look at salt under a microscope, you can see that each grain of salt is a perfect cube. The cubes form naturally as the salt comes out of solution. They are called salt ‘crystals’. All salt crystals are the same shape, but they may be different sizes.



Many chemicals form crystals. Sugar makes crystals and so does water when it turns to frost or snow. Each type of crystal has its own shape. Most rocks are made of crystals of chemical compounds called ‘minerals’. Granite is made up of crystals of ‘quartz’, ‘feldspar’ and ‘mica’. Crystals of diamond or emerald may be made into jewellery.



Salt crystals



Salt is made up of an equal number of sodium and chlorine atoms. When salt is in solution, these atoms are far apart. But as the water evaporates, the atoms get closer together. They always arrange themselves in the same way. This arrangement, called a ‘crystal lattice’, gives the salt its cubic shape.



Carbon



Carbon is an element: it is made up only of carbon atoms. But these atoms can arrange themselves in a number of ways to form several different types of carbon crystals. For example, charcoal is a soft black substance which can be used for drawing or may be burnt as a fuel; graphite is harder and is used to make the ‘lead’ in pencils. Surprisingly, diamonds are also pure carbon! Unlike charcoal and graphite, diamonds are extremely rare. They are used to make highly priced jewellery, and they also have industrial uses. Diamond is the hardest substance known and can be shaped to make cutting tools. Diamonds are also crystals of carbon. They are cut in a particular way to make them sparkle.



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What are Solutions?


Salt ‘disappears’ in water. But a taste of the liquid tells you that the salt is still there. So what has happened to the salt? When salt is mixed with water, the sodium and chlorine atoms break away from each other and move freely in the water. Gradually, the sodium and chlorine atoms and the water molecules are mixed up evenly. The liquid is called a salt ‘solution’. The salt has ‘dissolved’.



Many substances dissolve in water. Water is a good ‘solvent’. Carbon dioxide gas dissolves in water and makes it fizzy. Some substances dissolve in different solvents — paint dissolves in white spirit. Detergents ‘help’ water to dissolve oil.



Drops of oil floating on water will rush away from a drop of detergent added to the water. This is because detergent causes the surface of the water to change and the oil starts to dissolve.



Diffusion



If orange juice is poured down a straw into a glass of water, an orange patch forms in the middle of the water. The molecules of the water and the orange juice are moving all the time. Eventually, the orange molecules spread evenly throughout the water and the solution looks pale orange all over. This spreading of molecules is called ‘diffusion’.



Sea water is a massive solution of salt and water.



Oil-based paint does not dissolve in water, but it will dissolve in a solvent called white spirit.



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What are called Chemical Changes?


When water changes its state, its molecules are still made of hydrogen and oxygen — the chemical itself has not changed. When elements combine to make a compound, new molecules are formed. This is a ‘chemical change’.



We see examples of compounds forming every day. Most metals combine with chemicals in the air. Copper roofs slowly turn green as the copper combines with water and oxygen to form a new compound. An iron nail left outside soon starts to turn brown. The iron has reacted with water and oxygen in the air to form ‘rust’. Cars are made of several metals including iron. They have to be coated in paint to try to prevent them from rusting.



Baking a cake



When you bake a sponge cake, one of the ingredients used is baking powder. As it is heated in the oven, the baking powder breaks down into different chemicals. One of these is a gas — carbon dioxide. The bubbles of carbon dioxide throughout the sponge make it light and fluffy. The baked sponge is now a new mixture of many different compounds.



Copper roofs slowly turn green as the copper combines with oxygen to form a new compound.



Iron bridges need to be coated with chemicals to prevent them from rusting.



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What are basic phases of matter?


SOLIDS, LIQUIDS AND GASES



Chemicals may be solids, liquids or gases. Water is a liquid. When water is cooled to below 0°C it freezes and forms ice, a solid. When it is heated to 100°C it boils and changes to steam, a gas. We say that water can change its ‘state’.



A chemical’s state depends on its temperature. Solids may turn to liquids and gases and then back to solids again, as the temperature rises and falls. We usually see metals and rocks in their solid state. When they’re heated, they become softer. If they’re heated to a high enough temperature, they melt and become liquid.



Ice



Because the molecules in a solid, such as ice, are held firmly together and can only move about a fixed point, they have a definite shape.



Water



As a liquid, water molecules can move around more freely. The ‘shape’ of the water depends on the container.



Water vapour



The molecules in steam can move freely in all directions, spreading further and further apart until they fill their container.



In the Arctic, the temperature is so cold that sea water freezes into huge solid glaciers.



Steam is given off by cooling towers. The water vapour molecules move freely and spread apart.



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What is Chemical World?


Everything that exists — from the Sun in the sky to the centre of the Earth, and from animals to vegetables —is made up of chemicals. Many of these are familiar to us, such as water, salt, sugar, iron and oxygen. Chemicals can be different from each other in many ways. They have different tastes, like sugar and salt, or different appearances, like gold and silver. Chemicals come in many different forms; some are solids, others are liquids or gases.



Our world is composed of thousands of different substances. We call these substances ‘chemicals’. Chemicals make up the air we breathe, the ground we walk on and the food we eat. Even our bodies are a collection of chemicals!



Chemicals are often put into groups. Water, salt, sugar and oxygen are all chemicals. We call them ‘natural’ chemicals. Plastics, detergents and cosmetics are everyday chemicals too. But these do not occur naturally — they are ‘man-made’. Both types of chemicals are useful. Man-made cleaning agents remove dirt from our clothes and natural dyes from plants are used to colour fabrics.



Our food contains many different chemicals such as vitamins, proteins, fats, carbohydrates and sugars. Chemicals give fruit and vegetables their colour.



Water is made of chemicals and without it there would be no life on Earth.



Wool and cotton can be dyed with man-made chemicals or with natural chemicals from plants.



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